Lineage is a popular choice, see if your device is supported.
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I have /e/OS on s7 and s9
iodéOS supports some of the older Samsung devices (9 and 10 S and Note series). Unfortunately there are not many options if you have a newer Samsung.
Don't think you can unlock the bootloaders on Samsung devices, so not really possible
Most you can do to make it privacy friendlier (still not private) is to disable/uninstall app the bloat until you get to the minimum required apps, try to replace as many apps and you can with fdroid equivalents, and add an adblocking firewall. Settings your private DNS to dns.adguard-dns.com could probably help too.
This is the option I can enable after activating developer options on my Samsung. It is in spanish, but it do mean that you are able to unlock the OEM bootloader, letting you access to boot roms, as far as I understand. Is it really impossible?

It is very possible, samsung only locks down phones in northern america (where they're forced by the carriers)
You can use the leaked official tool (odin) or the foss reverse-engineered heimdall
If you are able to OEM unlock, you probably can flash a ROM of your choosing. Now find a rom that is compatible with your device.
As other have said, calyx, or lineage are good options. but if there are unofficial they are likely to have security vulnerabilities. If thats not a deal breaker for you than try it out.
Ps make sure you have a usb 2.0 or newer. a cheap usb 1.0 will not work.
Get adb and fastboot.
Let me know how it goes!
What is your phone model?
Could't find any custom roms but you could try this (originally made for a12 but should work for all A series phones)
Not on samsung
That's the point, fuck Samsung.
CalyxOS only supports pixel, fairphone, and shift
Not even xiaomi which is widely considered moddable
There are many reasons to hate samsung, calyxOS lack of support is not one of them
Posted from my samsung phone running degoogled lineageOS
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