The mole is defined based on the gram and not the kilogram, even though the kilogram is the coherent unit of mass. I don't have an example, but it probably results in a bit of extra math somewhere. Again, who knows why. Apparently the mole has had conflicting definitions in the past, and one of them was based on the kilogram, so it seems like this would have been easy to do. Again, the gram is involved - maybe the two things are related?