Not to my knowledge.
But also, I would assume the vast majority of library licenses were from buying blu-rays. You buy a movie or a season/collection and get a card to get the digital copy with it. So people, theoretically, already have physical copies.
In large part because... funimation was "the good anime streaming service". That is similar to "Sony's network shit is good compared to Nintendo" and "I would rather get shot in the ass than the foot"
Still hot bullshit though considering that there IS another anime service with similar capabilities under the same company (crunchyroll). I understand license hell and all that but... still.