Molly is only available on Android, as far as differences it is a hardened fork of signal with an encrypted database, what that means in practice is even if someone was actively probing your phone to try to gain access to messages they wouldn't be able to due to the encryption. It's very useful if you are an active target or you don't trust your phone os to play nice. I personally use it myself and really like it but in general it's not terribly different.
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