Pick and choose. I actually like most of the Python Doc. Learned Python originally from their tutorial. Then learned key parts of the library. So I like those two documents. The other docs though can be deep. The language reference for example. Never read that except parts.

I also had a book about Tkinter and another about Win32 Python programming. So I learned from those too. My first app was a data acquisition too with a Tkinter GUI. So I think a few books are good but maybe people do not do that now.

For me, learned Python in a day mostly from their tutorial and the standard library reference, then it took me the next 9 months to actually get good at it. Then still learning stuff 25 years later. I did have an advantage. I had been programming for 20 years before I learned Python and had used half a dozen other languages.